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H 危险声明 + P 防范说明大全(中英对照)

GHS/CLP 化学品标签上的每一句警示都对应一个统一编号。本文一次列出常用 H、P、EUH 声明的中英对照。

GHS 全球化学品统一分类和标签制度用两套编号覆盖标签上的所有规范措辞:H 声明(Hazard Statements,危险性说明)P 声明(Precautionary Statements,防范说明)。欧盟 CLP 又追加了 EUH 声明。中国 GB 30000 系列采用相同编号体系,中文措辞已由国标固定。

一、编号体系

范围类别用途
H200-H299H 声明物理危险
H300-H399H 声明健康危险
H400-H499H 声明环境危险
P100-P199P 声明一般
P200-P299P 声明预防
P300-P399P 声明响应
P400-P499P 声明储存
P500-P599P 声明处置
EUH001+EUH 声明欧盟 CLP 补充

二、常用 H 声明 · 物理危险(H200 系列)

编号中文英文
H200不稳定爆炸物Unstable explosive
H201爆炸物;整体爆炸危险Explosive; mass explosion hazard
H220极易燃气体Extremely flammable gas
H222极易燃气雾剂Extremely flammable aerosol
H224极易燃液体和蒸气Extremely flammable liquid and vapour
H225高度易燃液体和蒸气Highly flammable liquid and vapour
H226易燃液体和蒸气Flammable liquid and vapour
H228易燃固体Flammable solid
H240加热可能爆炸Heating may cause an explosion
H242加热可能引起火灾Heating may cause a fire
H260遇水放出可自燃的易燃气体In contact with water releases flammable gases which may ignite spontaneously
H261遇水放出易燃气体In contact with water releases flammable gases
H270可能引起或加剧燃烧;氧化剂May cause or intensify fire; oxidiser
H272可能加剧燃烧;氧化剂May intensify fire; oxidiser
H280内含加压气体;遇热可能爆炸Contains gas under pressure; may explode if heated
H290可能对金属有腐蚀性May be corrosive to metals

三、常用 H 声明 · 健康危险(H300 系列)

编号中文英文
H300吞咽致命Fatal if swallowed
H301吞咽会中毒Toxic if swallowed
H302吞咽有害Harmful if swallowed
H304吞咽及进入呼吸道可能致命May be fatal if swallowed and enters airways
H310皮肤接触致命Fatal in contact with skin
H311皮肤接触会中毒Toxic in contact with skin
H314造成严重皮肤灼伤和眼损伤Causes severe skin burns and eye damage
H315造成皮肤刺激Causes skin irritation
H317可能导致皮肤过敏反应May cause an allergic skin reaction
H318造成严重眼损伤Causes serious eye damage
H319造成严重眼刺激Causes serious eye irritation
H330吸入致命Fatal if inhaled
H331吸入会中毒Toxic if inhaled
H332吸入有害Harmful if inhaled
H334吸入可能导致过敏或哮喘症状或呼吸困难May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335可能导致呼吸道刺激May cause respiratory irritation
H336可能导致困倦或眩晕May cause drowsiness or dizziness
H340可能导致遗传性缺陷May cause genetic defects
H341怀疑导致遗传性缺陷Suspected of causing genetic defects
H350可能致癌May cause cancer
H351怀疑致癌Suspected of causing cancer
H360可能损害生育力或胎儿May damage fertility or the unborn child
H361怀疑损害生育力或胎儿Suspected of damaging fertility or the unborn child
H370造成器官损害Causes damage to organs
H371可能造成器官损害May cause damage to organs
H372长期或反复接触会造成器官损害Causes damage to organs through prolonged or repeated exposure
H373长期或反复接触可能造成器官损害May cause damage to organs through prolonged or repeated exposure

四、常用 H 声明 · 环境危险(H400 系列)

编号中文英文
H400对水生生物毒性极大Very toxic to aquatic life
H410对水生生物毒性极大并具有长期持续影响Very toxic to aquatic life with long lasting effects
H411对水生生物有毒并具有长期持续影响Toxic to aquatic life with long lasting effects
H412对水生生物有害并具有长期持续影响Harmful to aquatic life with long lasting effects
H413可能对水生生物造成长期持续的有害影响May cause long lasting harmful effects to aquatic life
H420释放到上层大气会破坏臭氧层,危害公共健康和环境Harms public health and the environment by destroying ozone in the upper atmosphere

五、常用 P 声明 · 预防(P200 系列)

编号中文英文
P201使用前取得专项说明Obtain special instructions before use
P210远离热源、热表面、火花、明火以及其他点火源。禁止吸烟。Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220远离衣物和其他可燃材料Keep away from clothing and other combustible materials
P233保持容器密闭Keep container tightly closed
P240容器和接收设备接地并搭接Ground and bond container and receiving equipment
P241使用防爆的电气/通风/照明设备Use explosion-proof [electrical/ventilating/lighting] equipment
P260不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾Do not breathe dust/fume/gas/mist/vapours/spray
P262不得与眼睛、皮肤或衣物接触Do not get in eyes, on skin, or on clothing
P264操作后彻底清洗Wash thoroughly after handling
P270使用本产品时不要进食、饮水或吸烟Do not eat, drink or smoke when using this product
P271只能在室外或通风良好处使用Use only outdoors or in a well-ventilated area
P273避免释放到环境中Avoid release to the environment
P280戴防护手套/穿防护服/戴护眼罩/戴面罩Wear protective gloves/clothing/eye protection/face protection

六、常用 P 声明 · 响应(P300 系列,含组合声明)

响应类 P 声明通常成组使用,用 "+" 号连接:

编号中文英文
P301+P310如误吞咽:立即呼叫解毒中心/医生IF SWALLOWED: Immediately call a POISON CENTER/doctor
P301+P330+P331如误吞咽:漱口。不得引吐。IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352如皮肤接触:用大量肥皂和水清洗IF ON SKIN: Wash with plenty of soap and water
P303+P361+P353如皮肤(或头发)接触:立即脱掉所有污染的衣物。用水/淋浴清洗皮肤。IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340如误吸入:将人转移到新鲜空气处,保持呼吸舒适体位IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338如眼睛接触:小心用水冲洗几分钟。如戴隐形眼镜并可方便取出,取出隐形眼镜。继续冲洗。IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313如接触或有疑虑:寻求医疗建议/诊治IF exposed or concerned: Get medical advice/attention
P370+P378火灾时:使用[适宜的灭火介质]灭火In case of fire: Use [suitable extinguishing media] to extinguish
P391收集溢出物Collect spillage

七、常用 P 声明 · 储存与处置

编号中文英文
P402存放在干燥处Store in a dry place
P403+P233存放于通风良好处。保持容器密闭。Store in a well-ventilated place. Keep container tightly closed.
P403+P235存放于通风良好处。保持低温。Store in a well-ventilated place. Keep cool.
P405存放处须加锁Store locked up
P410+P412避免阳光直射。存放温度不超过 50°C。Protect from sunlight. Do not expose to temperatures exceeding 50°C.
P411存放温度不超过 [X]°CStore at temperatures not exceeding [X]°C
P501按当地/地区/国家/国际法规处置内容物和容器Dispose of contents/container in accordance with local/regional/national/international regulations

八、欧盟 EUH 补充声明

编号中文英文
EUH014遇水剧烈反应Reacts violently with water
EUH029遇水放出有毒气体Contact with water liberates toxic gas
EUH031遇酸放出有毒气体Contact with acids liberates toxic gas
EUH059对臭氧层有害Hazardous to the ozone layer
EUH066反复接触可能引起皮肤干燥或皲裂Repeated exposure may cause skin dryness or cracking
EUH070眼接触会中毒Toxic by eye contact
EUH071对呼吸道有腐蚀性Corrosive to the respiratory tract
EUH201含铅。不得用于可能被儿童啃咬或吮吸的物品表面。Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
EUH208含 [致敏物质名称]。可能引起过敏反应。Contains [name of sensitising substance]. May produce an allergic reaction.
EUH210索取安全数据表Safety data sheet available on request

九、选择声明的基本原则

  1. H 声明是强制的:分类为某危险类别就必须标注其对应的 H 声明(GB 30000/CLP Annex I 中已指定)。
  2. P 声明是选用的:标签上通常不超过 6 条 P 声明,超过时须体现危害性质和严重性。
  3. P 声明中的方括号内容须替换为实际值(如温度、适宜灭火介质、致敏物名称)。
  4. 不适用的分支应删除(例如"如误吸入"分支只在有吸入风险时保留)。
  5. 建议按预防 → 响应 → 储存 → 处置顺序排列。

相关工具

参考:Regulation (EC) No 1272/2008 Annex III 和 IV(合并版);UN GHS Rev.10 Annex 3;GB 30000.2~30000.29-2013 附录。中文措辞以最新国标为准。